Synthesis and Metal Complex Formation of a Bis(terpyridine) Derivative with a Phenylacetylene Framework

Tokizaki, Tomoyuki; Toyoshima, Takuya; Watanabe, Soichiro

doi:10.6084/m9.figshare.1181987.v3

lsyc_a_952306_sm4637.pdf (1.13 MB)

Synthesis and Metal Complex Formation of a Bis(terpyridine) Derivative with a Phenylacetylene Framework

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journal contribution

posted on 2014-11-26, 05:48 authored by Tomoyuki Tokizaki, Takuya Toyoshima, Soichiro Watanabe

A new bis(terpyridine) derivative with a phenylacetylene framework was synthesized via a stepwise terpyridine construction strategy. The addition of ZnCl₂ to a solution of the bis(terpyridine) in chloroform resulted in UV/vis and ¹H NMR spectral changes because of complex formation.